Which amines can undergo diazotization?

14.4: Diazotization of Amines

• Primary Amines.
• Secondary Amines.
• Aryl Amines. 2º-Aryl Amines: 3º-Aryl Amines:
• Further Reading.

How do primary amines react?

Primary amines react with nitrous acid to yield a diazonium salt, which is highly unstable and degradates into a carbocation that is capable of reaction with any nucleophile in solution. Therefore, reacting primary amines with nitrous acid leads to a mixture of alcohol, alkenes, and alkyl halides.

What is diazotization reaction explain by reaction?

The chemical process used in converting a primary aromatic amine into the corresponding diazonium salt of the amine is commonly referred to as diazotization. Generally, the preparation of these diazonium salts involves the reaction of an aromatic amine with nitrous acid in the presence of another acid.

What is the mechanism of the diazotization reaction?

Diazotization reaction mechanism generally involves the usage of nitrous acid and another acid in the treatment of aromatic amines in order to yield the diazonium salt. What is Diazotization? The chemical process used in converting a primary aromatic amine into the corresponding diazonium salt of the amine is commonly referred to as diazotization.

What happens to aliphatic amines after diazotization?

The intermediates resulting from the diazotization of primary, aliphatic amines are unstable; they are rapidly converted into carbocations after loss of nitrogen, and yield products derived from substitution, elimination or rearrangement processes.

How is diazonium salt converted to primary aromatic amine?

The chemical process used in converting a primary aromatic amine into the corresponding diazonium salt of the amine is commonly referred to as diazotization. This process is also known as ‘diazotation’ .

Who was the first person to report the diazotization reaction?

The chemical process used in converting a primary aromatic amine into the corresponding diazonium salt of the amine is commonly referred to as diazotization. This process is also known as ‘diazotization’. The German industrial chemist Peter Griess was the first person to report such a reaction in 1858.